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2022-05-03

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Divyabharathi, R., Subramanian, P., 2022. Assessment of product yield and characteristics of biocrude from hydrothermal liquefaction. Research Biotica 4(2), 42-46. DOI: 10.54083/ResBio/4.2.2022/42-46.

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HOME / ARCHIVES / Vol. 4 No. 2 : April-June (2022) / Research Articles

Assessment of Product Yield and Characteristics of Biocrude from Hydrothermal Liquefaction

R. Divyabharathi*

Dept. of Renewable Energy Engineering, Agricultural Engineering College and Research Institute, Tamil Nadu Agricultural University, Coimbatore, Tamil Nadu (641 003), India

P. Subramanian

Dept. of Renewable Energy Engineering, Agricultural Engineering College and Research Institute, Tamil Nadu Agricultural University, Coimbatore, Tamil Nadu (641 003), India

DOI: https://doi.org/10.54083/ResBio/4.2.2022/42-46

Keywords: Biocrude, FTIR, GC-MS, Hydrothermal liquefaction, Wet biomass, Wine waste

Abstract


Biomass is a promising renewable energy source for fuel conversion. Hydrothermal liquefaction technology converts biomass into an energy-rich biofuel called biocrude which can potentially substitute fossil fuels. In this study, wet biomass namely water hyacinth, banana pseudostem, banana peduncle, wine waste and beer waste were investigated for biocrude production. The biomass macro molecules underwent anaerobic thermochemical disintegration to yield biocrude in the range of 7.3 to 16% at the hydrothermal liquefaction temperature and pressure of 275 ºC and 15 MPa respectively. Wine waste showed higher biocrude yield (16%) among the selected biomass materials with aqueous phase (63%) and char (3%) as by products. The recovered biocrude showed good quality fuel properties similar to diesel and bio-diesel with heating value of about 30 MJ kg-1. GCMS and FTIR analyses proved the biocrude to be rich in aliphatic and aromatic fuel and chemical derivatives of alkenes, alcohols, ketones and amines which necessitate its potential to drop in advanced fuels and chemicals for supplementing conventional resources.

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ASTM, D 3174-89, D 3175-89, 1989. Standards test methods for ash and volatile matter in the analysis sample of coal and coke in gaseous fuels. In: Annual Book of ASTM Standards. ASTM International., West Conshohocken, PA. pp. 302-305.

ASTM, D92-16b, D5002-16, D7042-16e3, 2016. Standard Test Methods for Flash and Fire Points, Dynamic Viscosity, Density and Relative Density of Crude Oils. ASTM International, West Conshohocken, PA. pp. 36-84.

ASTM, D5771-17, D5853-17, D4868-17, 2017. Standard Test Methods for Cloud Point, Pour point, Net and Gross Heat of combustion of Petroleum Products and Liquid Fuels. ASTM International, West Conshohocken, PA. pp. 942-959.

Biller, P., Ross, A.B., 2011. Potential yields and properties of oil from the hydrothermal liquefaction of microalgae with different biochemical content. Bioresource Technology 102, 215-225.

Divyabharathi, R., Subramanian, P., 2022. Biocrude production from orange (Citrus reticulata) peel by hydrothermal liquefaction and process optimization. Biomass Conversion and Biorefinery 12, 183-194.

Huber, G.W., Iborra, S., Corma, A., 2006. Synthesis of transportation fuels from biomass: Chemistry, catalysts and engineering. Chemical Reviews 106, 4044-4098.

Isa, K.M., Daudb, S., Hamidina, N., Ismailc, K., Saada, S.A., Kasim, F.H., 2011. Thermogravimetric analysis and the optimisation of bio-oil yield from fixed-bed pyrolysis of rice husk using response surface methodology (RSM). Industrial Crops and Products 33, 481-487.

Koochaki, C.B., Khajavi, R., Rashidi, A., Mansouri, N., Yazdanshenas, M.E., 2020. The effect of pre-swelling on the characteristics of obtained activated carbon from cigarette butts fibers. Biomass Conversion and Biorefinery 10, 227-236.

Li, H., Liu, Z., Zhang, Y., Li, B., Lu, H., Duan, N., Liu, M., Zhu, Z., Si, B., 2014. Conversion efficiency and oil quality of low-lipid high-protein and high-lipid low-protein microalgae via hydrothermal liquefaction. Bioresource Technology 154, 322-329.

Li, H., Zhu, Z., Lu, J., Watson, J., Kong, D., Wang, K., Zhang, Y., Liu, Z., 2020. Establishment and performance of a plug-flow continuous hydrothermal reactor for biocrude oil production. Fuel 280, 118605.

Minowa, T., Kondo, T., Sudirjo, S., 1998. Thermochemical liquefaction of Indonesian biomass residues. Biomass and Bioenergy 14, 517-524.

MNRE, 2022. Bioenergy Overview. Ministry of New and Renewable Energy, Government of India. Available at: https://mnre.gov.in/bio-energy/current-status. Accessed on: 12 January, 2022.

NREL, 2012. Determination of Structural Carbohydrates and Lignin in Biomass. In: Laboratory Analytical Procedure. National Renewable Energy Laboratory, Golden, CO, USA. pp. 510-618.

NREL, 2016. Biodiesel Handling and Use Guide, 5th Edition. National Renewable Energy Laboratory, Golden, CO, USA. pp. 8-12.

Ramirez, J.A., Brown, R.J., Rainey, T.J., 2015. A review of hydrothermal liquefaction bio-crude properties and prospects for upgrading to transportation fuels. Energies 8, 6765-6794.

Shah, A.A., Toor, S.S., Seehar, T.H., Nielsen, R.S., Nielsen, A.H., Pedersen, T.H., Rosendahl, L.A., 2020. Bio-crude production through aqueous phase recycling of hydrothermal liquefaction of sewage sludge. Energies 13(2), 493.

Sharma, K., Pedersen, T.H., Toor, S.S., Schuurman, Y., Rosendahl, L.A., 2020. Detailed investigation of compatibility of hydrothermal liquefaction derived biocrude oil with fossil fuel for corefining to drop-in biofuels through structural and compositional analysis. ACS Sustainable Chemistry & Engineering 8(22), 8111-8123.

Xiu, S.N., Shahbazi, A., Shirley, V., Cheng, D., 2010. Hydrothermal pyrolysis of swine manure to bio-oil: Effects of operating parameters on products yield and characterization of bio-oil. Journal of Analytical and Applied Pyrolysis 88(1), 73-79.